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-By combining TA and TG measurements, we have described the complex third-order, 2D susceptibility of the 1S resonance of PbSe quantum dots.
-We have demonstrated a parameter extraction procedure that is reproducible for different quantum dot samples, and that some of the parameters, such as the pure dephasing time, are batch dependent.
-Inhomogeneity, exciton-induced broadening, exciton-exciton coulombic coupling shifts, and intraband absorption are all required to reconcile both datasets.
-TA features about 1S exciton band are not exclusively assigned as 1S transitions, which can have important consequences for interpreting the evolution of the 1S bleach.
-
-While the TA spectra show prominent 1S-resonant features, the intraband absorption and its associated refractive index signature are most visible in the TG dataset, so that disentangling the 1S resonant response and the broadband response is a more well-defined problem when both datasets are used together.
-This approach is thus useful for characterization of non-linear signals in spectrally congested systems.