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Diffstat (limited to 'PEDOT_PSS/chapter.tex')
| -rw-r--r-- | PEDOT_PSS/chapter.tex | 14 |
1 files changed, 8 insertions, 6 deletions
diff --git a/PEDOT_PSS/chapter.tex b/PEDOT_PSS/chapter.tex index 24702d1..622f8e4 100644 --- a/PEDOT_PSS/chapter.tex +++ b/PEDOT_PSS/chapter.tex @@ -37,14 +37,16 @@ even more structural inhomogeneity. In summary, PEDOT:PSS has a complex, nested microstructure. % From smallest to largest: \begin{ditemize} - \item PEDOT oligomers (6---18-mers) % [CITE 14] + \item PEDOT oligomers (6---18-mers) \cite{KirchmeyerStephan2005a} \item these oligomers $\pi$-stack to form small nanocrystalites, 3 to 14 oligomers for pristine - films to as many as 13---14 oligomers for more conductive solvent treated films % [CITE 15] + films to as many as 13---14 oligomers for more conductive solvent treated films + \cite{TakanoTakumi2012a} \item nanocrystallites then arrange into globular conductive particles in a pancake-like shape - % [CITE 16, 17] + \cite{NardesAlexandreMantovani2007a, NardesAlexandreMantovani2008a} \item these particles themselves are then linked via PSS-rich domains and assembled into - nanofibril geometry akin to a string of pearls %[CITE 6, 21] - \item nanofibrils interweave to form thin films, with PSS capping layer at surface %[CITE 19, 22] + nanofibril geometry akin to a string of pearls \cite{KimNara2013a, vandeRuitKevin2013a} + \item nanofibrils interweave to form thin films, with PSS capping layer at surface + \cite{TimpanaroS2004a} \end{ditemize} In order to be conductive, PEDOT:PSS needs to have good spatial and energetic overlap between @@ -283,7 +285,7 @@ The lines of constant $T_2$ span from $\Delta_{\mathsf{inhom}} = 0$ (green left the limit $\Delta_{\mathsf{inhom}} \rightarrow \infty$ (blue right ends of curves). % The lines of constant $T_2$ demonstrate that ensemble dephasing reduces the transient duration and introduces a peak shift. % -The influence of inhomogeneity on the observables vanishes as $T_2 \rightarrow \infty$. % +The influence of inhomogeneity on the observables vanishes as $T_2 \rightarrow \infty$. % We preformed simulations analogus to those in \autoref{pps:fig:parametric} for pulse durations longer and smaller than $\Delta_t = 40$ fs. % |