From b6aa31ec63513a30fdaaeb2ae18ab13fa1fc60a1 Mon Sep 17 00:00:00 2001 From: Blaise Thompson Date: Fri, 13 Apr 2018 08:46:31 -0500 Subject: 2018-04-13 08:46 --- MX2/chapter.tex | 20 +++++++++++++++++--- PEDOT_PSS/chapter.tex | 42 +++++++++++++++++++++++++++++++----------- abstract.tex | 17 ++++++++--------- bibliography.bib | 43 +++++++++++++++++++++++++++++-------------- dissertation.tex | 35 +++++++++++++++++------------------ todo.org | 38 ++++++++++++++++++++++---------------- 6 files changed, 124 insertions(+), 71 deletions(-) diff --git a/MX2/chapter.tex b/MX2/chapter.tex index 88b496e..6e5bdb1 100644 --- a/MX2/chapter.tex +++ b/MX2/chapter.tex @@ -1,6 +1,20 @@ -\chapter{Transition metal dichalcogenide thin films} \label{cha:mx2} - -\textit{This Chapter borrows extensively from \textcite{CzechKyleJonathan2015a}.} +\chapter{Measurement of Ultrafast Excitonic Dynamics of Few-Layer MoS$\mathbf{_2}$ using + State-Selective Coherent Multidimensional Spectroscopy} \label{cha:mx2} + +\textit{This Chapter borrows extensively from \textcite{CzechKyleJonathan2015a}. The authors are: + \begin{denumerate} + \item Kyle J. Czech + \item Blaise J. Thompson + \item Schuyler Kain + \item Qi Ding + \item Melinda J. Shearer + \item Robert J. Hamers + \item Song Jin + \item John C. Wright + \end{denumerate} +} + +\clearpage We report the first coherent multidimensional spectroscopy study of a MoS\textsubscript{2} film. % A four-layer sample of MoS\textsubscript{2} was synthesized on a silica substrate by a simplified diff --git a/PEDOT_PSS/chapter.tex b/PEDOT_PSS/chapter.tex index 10c5af2..b7fba1f 100644 --- a/PEDOT_PSS/chapter.tex +++ b/PEDOT_PSS/chapter.tex @@ -1,6 +1,28 @@ -\chapter{PEDOT:PSS} - -\section{Introduction} +\chapter{PEDOT:PSS} \label{cha:pps} + + +\textit{This Chapter presents content first published in \textcite{HorakErikH2018a}. + The authors are: + \begin{denumerate} + \item Erik H. Horak + \item Morgan T. Rea + \item Kevin D. Heylman + \item David Gelbwaser-Klimovsky + \item Semion K. Saikin + \item Blaise J. Thompson + \item Daniel D. Kohler + \item Kassandra A. Knapper + \item Wei Wei + \item Feng Pan + \item Padma Gopalan + \item John C. Wright + \item Alán Aspuru-Guzik + \item Randall H. Goldsmith + \end{denumerate} + This Chapter focuses on my contribution. % +} + +\section{Introduction} % ========================================================================= Poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS) is a transparent, electrically conductive (up to 4380 S cm$^{-1}$ \cite{KimNara2013a}) polymer. % @@ -15,7 +37,7 @@ even more structural inhomogeneity. % Nonlinear spectroscopy may be able to shed light on the microscopic environment of electronic states within PEDOT:PSS. % -\section{Background} +\section{Background} % =========================================================================== Complex microstructure: \begin{enumerate} @@ -38,7 +60,7 @@ These electronic perturbations arise from injected holes producing a quinoidal d over 4-5 monomers of the CP aromatic backbone, collectively called a polaron. % Energetically favorable to be spin-silent bipolaron. % -\section{Methods} +\section{Methods} % ============================================================================== PEDOT:PSS (Orgacon Dry, Sigma Aldrich) was dropcast onto a glass microscope slide at 1 mg/mL at a tilt to ensure homogeneous film formation. % @@ -65,7 +87,7 @@ Signal was detected using an InSb photodiode (Teledyne Judson J10D-M204-R01M-3C- Four wave mixing was isolated from excitation scatter using dual chopping and digital signal processing. % -\section{Transmittance and reflectance} +\section{Transmittance and reflectance} % ======================================================== \autoref{fig:PEDOTPSS_linear} shows the transmission, reflectance, and extinction spectrum of the thin film used in this work. % @@ -83,7 +105,7 @@ thin film used in this work. % \end{figure} \clearpage -\section{Three-pulse echo spectroscopy} % -------------------------------------------------------- +\section{Three-pulse echo spectroscopy} % ======================================================== Two dimensional $\tau_{21}, \tau_{22^\prime}$ scans were taken for two phase matching configurations: (1) $k_{\mathsf{out}} = k_1 - k_2 + k_{2^\prime}$ (3PE) and (2) $k_{\mathsf{out}} = @@ -296,8 +318,6 @@ Regardless, these contributions do not affect our analysis. % Extremely fast (single fs) carrier scattering time constants have also been observed for PEDOT-base conductive films. [CITES] -\section{Frequency-domain transient grating spectroscopy} % -------------------------------------- - -This section describes preliminary, unpublished work accomplished on PEDOT:PSS. % - +\section{Conclusions} % ========================================================================== +% TODO \ No newline at end of file diff --git a/abstract.tex b/abstract.tex index 1a1060d..fdaf7b9 100644 --- a/abstract.tex +++ b/abstract.tex @@ -22,9 +22,8 @@ tunable output frequencies. % These pulses are directed into a material under investigation. % The pulses interact with the material, and due to the specific interference between the multiple fields the material is driven to emit a new pulse: the MR-CMDS signal. % -This signal may be different in frequency from the input pulses, and it may travel in a new -direction depending on the exact experiment being performed. % -% BJT: flip proceeding sentence around +This signal may have a different frequency and/or direction than the input pulses, depending on the +exact experiment being performed. % The MR-CMDS experiment involves tracking the intensity of this output signal as a function of different properties of the excitation pulses. % These properties include @@ -40,12 +39,12 @@ Because MR-CMDS is a family of related-but-separate experiments, each of them a space, there are special challenges that must be addressed when designing a general-purpose MR-CMDS instrument. % BJT: be more specific about the challenge at hand These issues require development of software, hardware, and theory. % -Five different improvements to MR-CMDS are presented in this dissertation: 1. processing software -(\autoref{cha:pro}), 2. acquisition software (\autoref{cha:acq}) 3, active artifact correction -(\autoref{cha:act}), 4. automated OPA calibration (\autoref{cha:opa}), and 5. finite pulse -accountancy (\autoref{cha:mix}). % \hyperref[prt:background]{Part I: Background} introduces relevant literature which informs on this development work. % +\hyperref[prt:development]{Part II: Development} presents five strategies used to improve MR-CMDS: +1. processing software (\autoref{cha:pro}), 2. acquisition software (\autoref{cha:acq}) 3, active +artifact correction (\autoref{cha:act}), 4. automated OPA calibration (\autoref{cha:opa}), and 5. +finite pulse accountancy (\autoref{cha:mix}). % Finally, \hyperref[prt:applications]{Part III: Applications} presents three examples where these -instruments, with these improvements, have been used to address chemical questions in -semiconductor systems. % \ No newline at end of file +instruments, with these improvements, have been used to address chemical questions in semiconductor +systems. % \ No newline at end of file diff --git a/bibliography.bib b/bibliography.bib index f0d3d2d..86191ef 100644 --- a/bibliography.bib +++ b/bibliography.bib @@ -1177,6 +1177,21 @@ year = {1998} month = {nov}, } +@article{HorakErikH2018a, + author = {Horak, Erik H. and Rea, Morgan T. and Heylman, Kevin D. and Gelbwaser-Klimovsky, + David and Saikin, Semion K. and Thompson, Blaise J. and Kohler, Daniel D. and + Knapper, Kassandra A. and Wei, Wei and Pan, Feng and Gopalan, Padma and Wright, + John C. and Aspuru-Guzik, Alán and Goldsmith, Randall H.}, + title = {Exploring Electronic Structure and Order in Polymers via Single-Particle + Microresonator Spectroscopy}, + journal = {Nano Letters}, + volume = 18, + number = 3, + pages = {1600-1607}, + year = 2018, + doi = {10.1021/acs.nanolett.7b04211}, +} + @article{HunterJohnD2007a, author = {John D. Hunter}, title = {Matplotlib: A 2D Graphics Environment}, @@ -3060,6 +3075,20 @@ year = {1998} month = {jan}, } +@article{YursLenaA2011a, + author = {Yurs, Lena A and Block, Stephen B. and Pakoulev, Andrei V and Selinsky, Rachel S. + and Jin, Song and Wright, John}, + title = {Multiresonant Coherent Multidimensional Electronic Spectroscopy of Colloidal PbSe + Quantum Dots}, + journal = {The Journal of Physical Chemistry C}, + volume = 115, + number = 46, + pages = {22833--22844}, + year = 2011, + doi = {10.1021/jp207273x}, + month = {nov}, +} + @article{YursLenaA2012a, author = {Yurs, Lena A and Block, Stephen B and Pakoulev, Andrei V. and Selinsky, Rachel S. and Jin, Song and Wright, John}, @@ -3075,20 +3104,6 @@ year = {1998} month = {mar}, } -@article{YursLenaA2011a, - author = {Yurs, Lena A and Block, Stephen B. and Pakoulev, Andrei V and Selinsky, Rachel S. - and Jin, Song and Wright, John}, - title = {Multiresonant Coherent Multidimensional Electronic Spectroscopy of Colloidal PbSe - Quantum Dots}, - journal = {The Journal of Physical Chemistry C}, - volume = 115, - number = 46, - pages = {22833--22844}, - year = 2011, - doi = {10.1021/jp207273x}, - month = {nov}, -} - @article{ZanniMartinT2001a, author = {Zanni, Martin T and Asplund, Matthew C and Hochstrasser, Robin M}, title = {{Two-dimensional heterodyned and stimulated infrared photon echoes of diff --git a/dissertation.tex b/dissertation.tex index e1a3014..bff81b7 100644 --- a/dissertation.tex +++ b/dissertation.tex @@ -64,21 +64,21 @@ This dissertation is approved by the following members of the Final Oral Committ \include{introduction/chapter} \part{Background} \label{prt:background} -%\include{spectroscopy/chapter} -%\include{software/chapter} % sof +\include{spectroscopy/chapter} +\include{software/chapter} % sof \part{Development} \label{prt:development} -%\include{processing/chapter} % pro -%\include{acquisition/chapter} % acq -%\include{active_correction/chapter} % act -%\include{opa/chapter} % opa -%\include{mixed_domain/chapter} +\include{processing/chapter} % pro +\include{acquisition/chapter} % acq +\include{active_correction/chapter} % act +\include{opa/chapter} % opa +\include{mixed_domain/chapter} \part{Applications} \label{prt:applications} \include{PbSe_susceptibility/chapter} % pss \include{PbSe_global_analysis/chapter} % psg -%\include{MX2/chapter} -%\include{PEDOT_PSS/chapter} +\include{MX2/chapter} % mx2 +\include{PEDOT_PSS/chapter} % pps % appendix ----------------------------------------------------------------------------------------- @@ -86,16 +86,15 @@ This dissertation is approved by the following members of the Final Oral Committ \part{Appendix} \label{prt:appendix} \begin{appendix} -%\include{public/chapter} -%\include{procedures/chapter} -%\include{hardware/chapter} -% TODO: consider inserting WrightTools documentation as PDF -%\include{irf/chapter} -%\include{quantitative_ta/chapter} -%\include{tg/chapter} -%\include{opa_phase/chapter} % rpa +% AFTER DEFENSE \include{public/chapter} +\include{procedures/chapter} +\include{hardware/chapter} +\include{irf/chapter} +\include{quantitative_ta/chapter} +\include{tg/chapter} +\include{opa_phase/chapter} % rpa %\include{errata/chapter} -%\include{colophon/chapter} +% AFTER DEFENSE \include{colophon/chapter} \end{appendix} % post -------------------------------------------------------------------------------------------- diff --git a/todo.org b/todo.org index f6d000a..45021e4 100644 --- a/todo.org +++ b/todo.org @@ -1,20 +1,21 @@ -* TODO headers :introduction: -* TODO cite important CMDS discoveries, reviews :introduction: -* TODO incorporate Nancy's comments :introduction: -* TODO incorporate Claire's comments :introduction: -* TODO summarize PbSe chapter :introduction: -* TODO summarize MX2 chapter :introduction: -* TODO summarize PEDOT:PSS chapter :introduction: -* TODO verify light-matter interaction content :spectroscopy: -* TODO finish instrumentation section (darien) :spectroscopy: -* IDEA linear vs multidimensional figure :spectroscopy: -* IDEA see Paul's dissertation :spectroscopy: +* TODO headers :int: +* TODO cite important CMDS discoveries, reviews :int: +* TODO incorporate Nancy's comments :int: +* TODO incorporate Claire's comments :int: +* TODO summarize PbSe chapter :int: +* TODO summarize MX2 chapter :int: +* TODO summarize PEDOT:PSS chapter :int: +* TODO verify light-matter interaction content :spc: +* TODO finish instrumentation section (darien) :spc: +* IDEA linear vs multidimensional figure :spc: +* IDEA see Paul's dissertation :spc: ** re: loss of resonance advantage with very fast pulses * TODO more references for object oriented programming :sof: ** in inbox * IDEA incorporate StoddenVictoria2016a :sof: * IDEA incorporate idea "most people over-trust software" :sof: * IDEA consider refactoring or expanding OOP section :sof: +* IDEA insert content from SI :mix: * TODO summary paragraphs in introduction :pro: * TODO finish discussing interpolation types :pro: ** TODO describe figure @@ -55,10 +56,15 @@ * TODO generalizability :opa: * TODO future directions :opa: * TODO figure captions :opa: -* TODO insert content from main :pss: -* TODO insert content from SI :pss: -* TODO insert content from main :psg: -* TODO insert content from SI :psg: -* TODO insert content from SI :mixed_domain: +* DONE insert content from main :pss: + CLOSED: [2018-04-12 Thu 21:04] +* IDEA insert content from SI :pss: +* DONE insert content from main :psg: + CLOSED: [2018-04-12 Thu 21:04] +* IDEA insert content from SI :psg: +* TODO include errata, remove errata as chapter :mx2: +* TODO better title :pps: +* TODO first draft :pps: +* IDEA unpublished data summary :pps: * TODO verify all references :polish: * TODO read through and make links where appropriate :polish: -- cgit v1.2.3