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Diffstat (limited to 'PEDOT_PSS')
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1 files changed, 31 insertions, 11 deletions
diff --git a/PEDOT_PSS/chapter.tex b/PEDOT_PSS/chapter.tex index 10c5af2..b7fba1f 100644 --- a/PEDOT_PSS/chapter.tex +++ b/PEDOT_PSS/chapter.tex @@ -1,6 +1,28 @@ -\chapter{PEDOT:PSS} - -\section{Introduction} +\chapter{PEDOT:PSS} \label{cha:pps} + + +\textit{This Chapter presents content first published in \textcite{HorakErikH2018a}. + The authors are: + \begin{denumerate} + \item Erik H. Horak + \item Morgan T. Rea + \item Kevin D. Heylman + \item David Gelbwaser-Klimovsky + \item Semion K. Saikin + \item Blaise J. Thompson + \item Daniel D. Kohler + \item Kassandra A. Knapper + \item Wei Wei + \item Feng Pan + \item Padma Gopalan + \item John C. Wright + \item Alán Aspuru-Guzik + \item Randall H. Goldsmith + \end{denumerate} + This Chapter focuses on my contribution. % +} + +\section{Introduction} % ========================================================================= Poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS) is a transparent, electrically conductive (up to 4380 S cm$^{-1}$ \cite{KimNara2013a}) polymer. % @@ -15,7 +37,7 @@ even more structural inhomogeneity. % Nonlinear spectroscopy may be able to shed light on the microscopic environment of electronic states within PEDOT:PSS. % -\section{Background} +\section{Background} % =========================================================================== Complex microstructure: \begin{enumerate} @@ -38,7 +60,7 @@ These electronic perturbations arise from injected holes producing a quinoidal d over 4-5 monomers of the CP aromatic backbone, collectively called a polaron. % Energetically favorable to be spin-silent bipolaron. % -\section{Methods} +\section{Methods} % ============================================================================== PEDOT:PSS (Orgacon Dry, Sigma Aldrich) was dropcast onto a glass microscope slide at 1 mg/mL at a tilt to ensure homogeneous film formation. % @@ -65,7 +87,7 @@ Signal was detected using an InSb photodiode (Teledyne Judson J10D-M204-R01M-3C- Four wave mixing was isolated from excitation scatter using dual chopping and digital signal processing. % -\section{Transmittance and reflectance} +\section{Transmittance and reflectance} % ======================================================== \autoref{fig:PEDOTPSS_linear} shows the transmission, reflectance, and extinction spectrum of the thin film used in this work. % @@ -83,7 +105,7 @@ thin film used in this work. % \end{figure} \clearpage -\section{Three-pulse echo spectroscopy} % -------------------------------------------------------- +\section{Three-pulse echo spectroscopy} % ======================================================== Two dimensional $\tau_{21}, \tau_{22^\prime}$ scans were taken for two phase matching configurations: (1) $k_{\mathsf{out}} = k_1 - k_2 + k_{2^\prime}$ (3PE) and (2) $k_{\mathsf{out}} = @@ -296,8 +318,6 @@ Regardless, these contributions do not affect our analysis. % Extremely fast (single fs) carrier scattering time constants have also been observed for PEDOT-base conductive films. [CITES] -\section{Frequency-domain transient grating spectroscopy} % -------------------------------------- - -This section describes preliminary, unpublished work accomplished on PEDOT:PSS. % - +\section{Conclusions} % ========================================================================== +% TODO
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