aboutsummaryrefslogtreecommitdiff
path: root/PEDOT_PSS
diff options
context:
space:
mode:
Diffstat (limited to 'PEDOT_PSS')
-rw-r--r--PEDOT_PSS/chapter.tex14
1 files changed, 8 insertions, 6 deletions
diff --git a/PEDOT_PSS/chapter.tex b/PEDOT_PSS/chapter.tex
index 24702d1..622f8e4 100644
--- a/PEDOT_PSS/chapter.tex
+++ b/PEDOT_PSS/chapter.tex
@@ -37,14 +37,16 @@ even more structural inhomogeneity.
In summary, PEDOT:PSS has a complex, nested microstructure. %
From smallest to largest:
\begin{ditemize}
- \item PEDOT oligomers (6---18-mers) % [CITE 14]
+ \item PEDOT oligomers (6---18-mers) \cite{KirchmeyerStephan2005a}
\item these oligomers $\pi$-stack to form small nanocrystalites, 3 to 14 oligomers for pristine
- films to as many as 13---14 oligomers for more conductive solvent treated films % [CITE 15]
+ films to as many as 13---14 oligomers for more conductive solvent treated films
+ \cite{TakanoTakumi2012a}
\item nanocrystallites then arrange into globular conductive particles in a pancake-like shape
- % [CITE 16, 17]
+ \cite{NardesAlexandreMantovani2007a, NardesAlexandreMantovani2008a}
\item these particles themselves are then linked via PSS-rich domains and assembled into
- nanofibril geometry akin to a string of pearls %[CITE 6, 21]
- \item nanofibrils interweave to form thin films, with PSS capping layer at surface %[CITE 19, 22]
+ nanofibril geometry akin to a string of pearls \cite{KimNara2013a, vandeRuitKevin2013a}
+ \item nanofibrils interweave to form thin films, with PSS capping layer at surface
+ \cite{TimpanaroS2004a}
\end{ditemize}
In order to be conductive, PEDOT:PSS needs to have good spatial and energetic overlap between
@@ -283,7 +285,7 @@ The lines of constant $T_2$ span from $\Delta_{\mathsf{inhom}} = 0$ (green left
the limit $\Delta_{\mathsf{inhom}} \rightarrow \infty$ (blue right ends of curves). %
The lines of constant $T_2$ demonstrate that ensemble dephasing reduces the transient duration and
introduces a peak shift. %
-The influence of inhomogeneity on the observables vanishes as $T_2 \rightarrow \infty$. %
+The influence of inhomogeneity on the observables vanishes as $T_2 \rightarrow \infty$. %
We preformed simulations analogus to those in \autoref{pps:fig:parametric} for pulse durations
longer and smaller than $\Delta_t = 40$ fs. %