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-rw-r--r--MX2/chapter.tex20
-rw-r--r--PEDOT_PSS/chapter.tex42
-rw-r--r--abstract.tex17
-rw-r--r--bibliography.bib43
-rw-r--r--dissertation.tex35
-rw-r--r--todo.org38
6 files changed, 124 insertions, 71 deletions
diff --git a/MX2/chapter.tex b/MX2/chapter.tex
index 88b496e..6e5bdb1 100644
--- a/MX2/chapter.tex
+++ b/MX2/chapter.tex
@@ -1,6 +1,20 @@
-\chapter{Transition metal dichalcogenide thin films} \label{cha:mx2}
-
-\textit{This Chapter borrows extensively from \textcite{CzechKyleJonathan2015a}.}
+\chapter{Measurement of Ultrafast Excitonic Dynamics of Few-Layer MoS$\mathbf{_2}$ using
+ State-Selective Coherent Multidimensional Spectroscopy} \label{cha:mx2}
+
+\textit{This Chapter borrows extensively from \textcite{CzechKyleJonathan2015a}. The authors are:
+ \begin{denumerate}
+ \item Kyle J. Czech
+ \item Blaise J. Thompson
+ \item Schuyler Kain
+ \item Qi Ding
+ \item Melinda J. Shearer
+ \item Robert J. Hamers
+ \item Song Jin
+ \item John C. Wright
+ \end{denumerate}
+}
+
+\clearpage
We report the first coherent multidimensional spectroscopy study of a MoS\textsubscript{2} film. %
A four-layer sample of MoS\textsubscript{2} was synthesized on a silica substrate by a simplified
diff --git a/PEDOT_PSS/chapter.tex b/PEDOT_PSS/chapter.tex
index 10c5af2..b7fba1f 100644
--- a/PEDOT_PSS/chapter.tex
+++ b/PEDOT_PSS/chapter.tex
@@ -1,6 +1,28 @@
-\chapter{PEDOT:PSS}
-
-\section{Introduction}
+\chapter{PEDOT:PSS} \label{cha:pps}
+
+
+\textit{This Chapter presents content first published in \textcite{HorakErikH2018a}.
+ The authors are:
+ \begin{denumerate}
+ \item Erik H. Horak
+ \item Morgan T. Rea
+ \item Kevin D. Heylman
+ \item David Gelbwaser-Klimovsky
+ \item Semion K. Saikin
+ \item Blaise J. Thompson
+ \item Daniel D. Kohler
+ \item Kassandra A. Knapper
+ \item Wei Wei
+ \item Feng Pan
+ \item Padma Gopalan
+ \item John C. Wright
+ \item Alán Aspuru-Guzik
+ \item Randall H. Goldsmith
+ \end{denumerate}
+ This Chapter focuses on my contribution. %
+}
+
+\section{Introduction} % =========================================================================
Poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS) is a transparent, electrically
conductive (up to 4380 S cm$^{-1}$ \cite{KimNara2013a}) polymer. %
@@ -15,7 +37,7 @@ even more structural inhomogeneity. %
Nonlinear spectroscopy may be able to shed light on the microscopic environment of electronic
states within PEDOT:PSS. %
-\section{Background}
+\section{Background} % ===========================================================================
Complex microstructure:
\begin{enumerate}
@@ -38,7 +60,7 @@ These electronic perturbations arise from injected holes producing a quinoidal d
over 4-5 monomers of the CP aromatic backbone, collectively called a polaron. %
Energetically favorable to be spin-silent bipolaron. %
-\section{Methods}
+\section{Methods} % ==============================================================================
PEDOT:PSS (Orgacon Dry, Sigma Aldrich) was dropcast onto a glass microscope slide at 1 mg/mL at a
tilt to ensure homogeneous film formation. %
@@ -65,7 +87,7 @@ Signal was detected using an InSb photodiode (Teledyne Judson J10D-M204-R01M-3C-
Four wave mixing was isolated from excitation scatter using dual chopping and digital signal
processing. %
-\section{Transmittance and reflectance}
+\section{Transmittance and reflectance} % ========================================================
\autoref{fig:PEDOTPSS_linear} shows the transmission, reflectance, and extinction spectrum of the
thin film used in this work. %
@@ -83,7 +105,7 @@ thin film used in this work. %
\end{figure}
\clearpage
-\section{Three-pulse echo spectroscopy} % --------------------------------------------------------
+\section{Three-pulse echo spectroscopy} % ========================================================
Two dimensional $\tau_{21}, \tau_{22^\prime}$ scans were taken for two phase matching
configurations: (1) $k_{\mathsf{out}} = k_1 - k_2 + k_{2^\prime}$ (3PE) and (2) $k_{\mathsf{out}} =
@@ -296,8 +318,6 @@ Regardless, these contributions do not affect our analysis. %
Extremely fast (single fs) carrier scattering time constants have also been observed for PEDOT-base
conductive films. [CITES]
-\section{Frequency-domain transient grating spectroscopy} % --------------------------------------
-
-This section describes preliminary, unpublished work accomplished on PEDOT:PSS. %
-
+\section{Conclusions} % ==========================================================================
+% TODO \ No newline at end of file
diff --git a/abstract.tex b/abstract.tex
index 1a1060d..fdaf7b9 100644
--- a/abstract.tex
+++ b/abstract.tex
@@ -22,9 +22,8 @@ tunable output frequencies. %
These pulses are directed into a material under investigation. %
The pulses interact with the material, and due to the specific interference between the multiple
fields the material is driven to emit a new pulse: the MR-CMDS signal. %
-This signal may be different in frequency from the input pulses, and it may travel in a new
-direction depending on the exact experiment being performed. %
-% BJT: flip proceeding sentence around
+This signal may have a different frequency and/or direction than the input pulses, depending on the
+exact experiment being performed. %
The MR-CMDS experiment involves tracking the intensity of this output signal as a function of
different properties of the excitation pulses. %
These properties include
@@ -40,12 +39,12 @@ Because MR-CMDS is a family of related-but-separate experiments, each of them a
space, there are special challenges that must be addressed when designing a general-purpose MR-CMDS
instrument. % BJT: be more specific about the challenge at hand
These issues require development of software, hardware, and theory. %
-Five different improvements to MR-CMDS are presented in this dissertation: 1. processing software
-(\autoref{cha:pro}), 2. acquisition software (\autoref{cha:acq}) 3, active artifact correction
-(\autoref{cha:act}), 4. automated OPA calibration (\autoref{cha:opa}), and 5. finite pulse
-accountancy (\autoref{cha:mix}). %
\hyperref[prt:background]{Part I: Background} introduces relevant literature which informs on this
development work. %
+\hyperref[prt:development]{Part II: Development} presents five strategies used to improve MR-CMDS:
+1. processing software (\autoref{cha:pro}), 2. acquisition software (\autoref{cha:acq}) 3, active
+artifact correction (\autoref{cha:act}), 4. automated OPA calibration (\autoref{cha:opa}), and 5.
+finite pulse accountancy (\autoref{cha:mix}). %
Finally, \hyperref[prt:applications]{Part III: Applications} presents three examples where these
-instruments, with these improvements, have been used to address chemical questions in
-semiconductor systems. % \ No newline at end of file
+instruments, with these improvements, have been used to address chemical questions in semiconductor
+systems. % \ No newline at end of file
diff --git a/bibliography.bib b/bibliography.bib
index f0d3d2d..86191ef 100644
--- a/bibliography.bib
+++ b/bibliography.bib
@@ -1177,6 +1177,21 @@ year = {1998}
month = {nov},
}
+@article{HorakErikH2018a,
+ author = {Horak, Erik H. and Rea, Morgan T. and Heylman, Kevin D. and Gelbwaser-Klimovsky,
+ David and Saikin, Semion K. and Thompson, Blaise J. and Kohler, Daniel D. and
+ Knapper, Kassandra A. and Wei, Wei and Pan, Feng and Gopalan, Padma and Wright,
+ John C. and Aspuru-Guzik, Alán and Goldsmith, Randall H.},
+ title = {Exploring Electronic Structure and Order in Polymers via Single-Particle
+ Microresonator Spectroscopy},
+ journal = {Nano Letters},
+ volume = 18,
+ number = 3,
+ pages = {1600-1607},
+ year = 2018,
+ doi = {10.1021/acs.nanolett.7b04211},
+}
+
@article{HunterJohnD2007a,
author = {John D. Hunter},
title = {Matplotlib: A 2D Graphics Environment},
@@ -3060,6 +3075,20 @@ year = {1998}
month = {jan},
}
+@article{YursLenaA2011a,
+ author = {Yurs, Lena A and Block, Stephen B. and Pakoulev, Andrei V and Selinsky, Rachel S.
+ and Jin, Song and Wright, John},
+ title = {Multiresonant Coherent Multidimensional Electronic Spectroscopy of Colloidal PbSe
+ Quantum Dots},
+ journal = {The Journal of Physical Chemistry C},
+ volume = 115,
+ number = 46,
+ pages = {22833--22844},
+ year = 2011,
+ doi = {10.1021/jp207273x},
+ month = {nov},
+}
+
@article{YursLenaA2012a,
author = {Yurs, Lena A and Block, Stephen B and Pakoulev, Andrei V. and Selinsky, Rachel S.
and Jin, Song and Wright, John},
@@ -3075,20 +3104,6 @@ year = {1998}
month = {mar},
}
-@article{YursLenaA2011a,
- author = {Yurs, Lena A and Block, Stephen B. and Pakoulev, Andrei V and Selinsky, Rachel S.
- and Jin, Song and Wright, John},
- title = {Multiresonant Coherent Multidimensional Electronic Spectroscopy of Colloidal PbSe
- Quantum Dots},
- journal = {The Journal of Physical Chemistry C},
- volume = 115,
- number = 46,
- pages = {22833--22844},
- year = 2011,
- doi = {10.1021/jp207273x},
- month = {nov},
-}
-
@article{ZanniMartinT2001a,
author = {Zanni, Martin T and Asplund, Matthew C and Hochstrasser, Robin M},
title = {{Two-dimensional heterodyned and stimulated infrared photon echoes of
diff --git a/dissertation.tex b/dissertation.tex
index e1a3014..bff81b7 100644
--- a/dissertation.tex
+++ b/dissertation.tex
@@ -64,21 +64,21 @@ This dissertation is approved by the following members of the Final Oral Committ
\include{introduction/chapter}
\part{Background} \label{prt:background}
-%\include{spectroscopy/chapter}
-%\include{software/chapter} % sof
+\include{spectroscopy/chapter}
+\include{software/chapter} % sof
\part{Development} \label{prt:development}
-%\include{processing/chapter} % pro
-%\include{acquisition/chapter} % acq
-%\include{active_correction/chapter} % act
-%\include{opa/chapter} % opa
-%\include{mixed_domain/chapter}
+\include{processing/chapter} % pro
+\include{acquisition/chapter} % acq
+\include{active_correction/chapter} % act
+\include{opa/chapter} % opa
+\include{mixed_domain/chapter}
\part{Applications} \label{prt:applications}
\include{PbSe_susceptibility/chapter} % pss
\include{PbSe_global_analysis/chapter} % psg
-%\include{MX2/chapter}
-%\include{PEDOT_PSS/chapter}
+\include{MX2/chapter} % mx2
+\include{PEDOT_PSS/chapter} % pps
% appendix -----------------------------------------------------------------------------------------
@@ -86,16 +86,15 @@ This dissertation is approved by the following members of the Final Oral Committ
\part{Appendix} \label{prt:appendix}
\begin{appendix}
-%\include{public/chapter}
-%\include{procedures/chapter}
-%\include{hardware/chapter}
-% TODO: consider inserting WrightTools documentation as PDF
-%\include{irf/chapter}
-%\include{quantitative_ta/chapter}
-%\include{tg/chapter}
-%\include{opa_phase/chapter} % rpa
+% AFTER DEFENSE \include{public/chapter}
+\include{procedures/chapter}
+\include{hardware/chapter}
+\include{irf/chapter}
+\include{quantitative_ta/chapter}
+\include{tg/chapter}
+\include{opa_phase/chapter} % rpa
%\include{errata/chapter}
-%\include{colophon/chapter}
+% AFTER DEFENSE \include{colophon/chapter}
\end{appendix}
% post --------------------------------------------------------------------------------------------
diff --git a/todo.org b/todo.org
index f6d000a..45021e4 100644
--- a/todo.org
+++ b/todo.org
@@ -1,20 +1,21 @@
-* TODO headers :introduction:
-* TODO cite important CMDS discoveries, reviews :introduction:
-* TODO incorporate Nancy's comments :introduction:
-* TODO incorporate Claire's comments :introduction:
-* TODO summarize PbSe chapter :introduction:
-* TODO summarize MX2 chapter :introduction:
-* TODO summarize PEDOT:PSS chapter :introduction:
-* TODO verify light-matter interaction content :spectroscopy:
-* TODO finish instrumentation section (darien) :spectroscopy:
-* IDEA linear vs multidimensional figure :spectroscopy:
-* IDEA see Paul's dissertation :spectroscopy:
+* TODO headers :int:
+* TODO cite important CMDS discoveries, reviews :int:
+* TODO incorporate Nancy's comments :int:
+* TODO incorporate Claire's comments :int:
+* TODO summarize PbSe chapter :int:
+* TODO summarize MX2 chapter :int:
+* TODO summarize PEDOT:PSS chapter :int:
+* TODO verify light-matter interaction content :spc:
+* TODO finish instrumentation section (darien) :spc:
+* IDEA linear vs multidimensional figure :spc:
+* IDEA see Paul's dissertation :spc:
** re: loss of resonance advantage with very fast pulses
* TODO more references for object oriented programming :sof:
** in inbox
* IDEA incorporate StoddenVictoria2016a :sof:
* IDEA incorporate idea "most people over-trust software" :sof:
* IDEA consider refactoring or expanding OOP section :sof:
+* IDEA insert content from SI :mix:
* TODO summary paragraphs in introduction :pro:
* TODO finish discussing interpolation types :pro:
** TODO describe figure
@@ -55,10 +56,15 @@
* TODO generalizability :opa:
* TODO future directions :opa:
* TODO figure captions :opa:
-* TODO insert content from main :pss:
-* TODO insert content from SI :pss:
-* TODO insert content from main :psg:
-* TODO insert content from SI :psg:
-* TODO insert content from SI :mixed_domain:
+* DONE insert content from main :pss:
+ CLOSED: [2018-04-12 Thu 21:04]
+* IDEA insert content from SI :pss:
+* DONE insert content from main :psg:
+ CLOSED: [2018-04-12 Thu 21:04]
+* IDEA insert content from SI :psg:
+* TODO include errata, remove errata as chapter :mx2:
+* TODO better title :pps:
+* TODO first draft :pps:
+* IDEA unpublished data summary :pps:
* TODO verify all references :polish:
* TODO read through and make links where appropriate :polish: